Publications
218. “Crystallization-Induced Flower-like Superstructures via Peptoid Helix Assembly.” Kai-Chieh Yang, Daniela M. Rivera Mirabal, Ronnie V. Garcia, Niko W. Vlahakis, Phong H. Nguyen, Shawn D. Mengel, Matthew Mecklenburg, Jose A. Rodriguez, M. Scott Shell, Craig J. Hawker, and Rachel A. Segalman. ACS Macro Letters 2024, 13. DOI: 10.1021/acsmacrolett.4c00039
217. “Ion and Water Dynamics in the Transition from Dry to Wet Conditions in Salt-Doped PEG.” Nico Marioni, Oscar Nordness, Zidan Zhang, Rahul Sujanani, Benny D. Freeman, Rachel A. Segalman, Raphaële J. Clément, and Venkat Ganesan. ACS Macro Letters 2024 13 (3), 341-347. DOI: 10.1021/acsmacrolett.4c00046
216. “Control over Conformational Landscapes of Polypeptoids by Monomer Sequence Patterning.” Audra J. DeStefano, Shawn D. Mengel, Morgan W. Bates, Sally Jiao, M. Scott Shell, Songi Han, and Rachel A. Segalman. Macromolecules, 2024, 57, 4, 1469–1477. DOI: 10.1021/acs.macromol.3c02338
215. “Nanoscale water–polymer interactions tune macroscopic diffusivity of water in aqueous poly(ethylene oxide) solutions.” Joshua D. Moon, Thomas R. Webber, Dennis Robinson Brown, Peter M. Richardson, Thomas M. Casey, Rachel A. Segalman, M. Scott Shell and Songi Han. Chemical Science, 2024, 15, 2495-2508. DOI: 10.1039/D3SC05377F
214. “Diffusely Charged Polymeric Zwitterions as Loosely Hydrated Marine Antifouling Coatings.” Shawn D. Mengel, Wen Guo, Guangyao Wu, John A. Finlay, Peter Allen, Anthony S. Clare, Riddhiman Medhi, Zhan Chen, Christopher K. Ober, and Rachel A. Segalman. Langmuir 2023, 40, 1, 282-290. DOI: 10.1021/acs.langmuir.3c02492
213. “Single-Molecule Polypeptoid Stretching Reveals the Effects of Charge Sequence on Chain Conformation.” Hoang P. Truong, Shawn Mengel, Beihang Yu, Rachel A. Segalman, and Omar A. Saleh. Macromolecules 2023, 56, 21, 8558–8564. DOI: 10.1021/acs.macromol.3c01221
212. “Polypeptoids, Exploring the Power of Sequence Control in a Photoresist for Extreme-Ultraviolet Lithography.” Florian Käfer, Chaoqiuyu Wang, Yuming Huang, Francesca Bard, Rachel Segalman, Christopher K. Ober. Advanced Materials Technologies 2023, 2301104. DOI: 10.1002/admt.202301104
211. “Mixed Ion–Electron-Conducting Polymer Complexes as High-Rate Battery Binders.” Gordon Pace, Alexandra Zele, Phong Nguyen, Raphaële J. Clément, and Rachel A. Segalman. Chemistry of Materials 2023 35 (19), 8101-8111. DOI: 10.1021/acs.chemmater.3c01587
210. “Engineering Soft, Elastic, and Conductive Polymers for Stretchable Electronics Using Ionic Compatibilization.” My Linh Le, Intanon Lapkriengkri, Kaitlin R. Albanese, Phong H. Nguyen, Cassidy Tran, Jacob R. Blankenship, Rachel A. Segalman, Christopher M. Bates, and Michael L. Chabinyc. Chemistry of Materials 2023 35 (17), 7301-7310. DOI: 10.1021/acs.chemmater.3c01685
209. “Tuning Transport via Interaction Strength in Cationic Conjugated Polyelectrolytes.” Gordon Pace, Oscar Nordness, Phong H. Nguyen, Yu-Jin Choi, Cassidy Tran, Raphaële J. Clément, and Rachel A. Segalman. Macromolecules 2023 56 (15), 6078-6085. DOI: 10.1021/acs.macromol.3c01206
208. “Probing Water and Ion Diffusion in Functional Hydrogel Membranes by PFG-NMR.” Oscar Nordness, Joshua D. Moon, Nico Marioni, Everett S. Zofchak, Peter M. Richardson, Matthew R. Landsman, Lynn E. Katz, Craig J. Hawker, Venkat Ganesan, Rachel A. Segalman, and Raphaële J. Clément. Macromolecules 2023 56 (12), 4669-4680. DOI: 10.1021/acs.macromol.3c00306
207. “A Coacervate-Based Mixed-Conducting Binder for High-Power, High-Energy Batteries.” Gordon T. Pace, My Linh Le, Raphaële J. Clément, and Rachel A. Segalman. ACS Energy Letters, 2023 8 (6), 2781-2788. DOI: 10.1021/acsenergylett.3c00829
206. “Role of Complexation Strength on the Photophysical and Transport Properties of Semiconducting Charged Polymer Complexes.” My Linh Le, Caleigh Warner, Rachel A. Segalman, and Michael L. Chabinyc. Chemistry of Materials, 2023 35 (11), 4449-4460. DOI: 10.1021/acs.chemmater.3c00627
205. “Compatibilization of Polymer Blends by Ionic Bonding.” Shuyi Xie, Kseniia M. Karnaukh, Kai-Chieh Yang, Dan Sun, Kris T. Delaney, Javier Read de Alaniz, Glenn H. Fredrickson, and Rachel A. Segalman. Macromolecules, 2023 56 (10), 3617-3630. DOI: 10.1021/acs.macromol.3c00060
204. “Photoresists with precisely controlled molecular weight, composition and sequence.” Florian Kaefer, Zoey Meng, Rachel Segalman, Javier Read de Alaniz, Christopher K. Ober. Proceedings Volume 12498, Advances in Patterning Materials and Processes XL, 2023, 124980F. DOI: 10.1117/12.2658582
203. “Sequence-defined polypeptoid CARs for electron-beam and EUV lithography.” Florian Kaefer, Christopher K. Ober, Zoey Meng, Rachel Segalman, Javier Read de Alaniz. Proceedings Volume 12498, Advances in Patterning Materials and Processes XL, 2023, 1249817. DOI: 10.1117/12.2658413
202. “Design of Soft Material Surfaces with Rationally Tuned Water Diffusivity.” Audra J. DeStefano, My Nguyen, Glenn H. Fredrickson, Songi Han, and Rachel A. Segalman. ACS Central Science, 2023, 9, 5, 1019-1024. DOI: 10.1021/acscentsci.3c00208
201. “Double Doping of Semiconducting Polymers Using Ion-Exchange with a Dianion.” Dafei Yuan, Evan Plunkett, Phong H. Nguyen, Dakota Rawlings, My Linh Le, Rene Kroon, Christian Müller, Rachel A. Segalman, Michael L. Chabinyc. Advanced Functional Materials, 2023. DOI: 10.1002/adfm.202300934
200. “Modular Synthesis and Patterning of High-Stiffness Networks by Postpolymerization Functionalization with Iron–Catechol Complexes” Declan P. Shannon, Joshua D. Moon, Christopher W. Barney, Nairiti J. Sinha, Kai-Chieh Yang, Seamus D. Jones, Ronnie V. Garcia, Matthew E. Helgeson, Rachel A. Segalman, Megan T. Valentine, and Craig J. Hawker. Macromolecules, 2023, 56, 6, 2268–2276. DOI: 10.1021/acs.macromol.2c02561
199. “Electrochemical Characterization of Biomolecular Electron Transfer at Conductive Polymer Interfaces.” Alec Agee, Thomas Mark Gill, Gordon Pace, Rachel Segalman and Ariel Furst. Journal of the Electrochemical Society, 2023, 170, 016509. DOI: 10.1149/1945-7111/acb239
198. “Controlled Sequence Peptoids as Photoresist Platforms for High-resolution DUV/EUV Photoresists.” X. Z. Meng, F. H. Käfer, G. M. Wallraff, C.K. Ober, R. A. Segalman, Proceedings Volume 12292, International Conference on Extreme Ultraviolet Lithography 2022, 122920Q. DOI: https://doi.org/10.1117/12.2642965
197. “Decoupling Ion Transport and Matrix Dynamics to Make High Performance Solid Polymer Electrolytes.” Seamus D. Jones, James Bamford, Glenn H. Fredrickson, and Rachel A. Segalman. ACS Polymers Au, 2022, 2 (6), 430-448. DOI: 10.1021/acspolymersau.2c00024
196. “Electrostatic Interactions Control the Nanostructure of Conjugated Polyelectrolyte–Polymeric Ionic Liquid Blends.” My Linh Le, Douglas J. Grzetic, Kris T. Delaney, Kai-Chieh Yang, Shuyi Xie, Glenn H. Fredrickson, Michael L. Chabinyc, and Rachel A. Segalman. Macromolecules, 2022, 55 (18), 8321–8331. DOI: 10.1021/acs.macromol.2c01142
195. “Ionic Compatibilization of Polymers.” Glenn H. Fredrickson, Shuyi Xie, Jerrick Edmund, My Linh Le, Dan Sun, Douglas J. Grzetic, Daniel L. Vigil, Kris T. Delaney, Michael L. Chabinyc, and Rachel A. Segalman. ACS Polymers Au, 2022, 2 (5), 299-312. DOI: 10.1021/acspolymersau.2c00026
194. “Polymer Electrolyte Based on Cyano-Functionalized Polysiloxane with Enhanced Salt Dissolution and High Ionic Conductivity.” Shuyi Xie, Andrei Nikolaev, Oscar A. Nordness, Luana C. Llanes, Seamus D. Jones, Peter M. Richardson, Hengbin Wang, Raphaële J. Clément, Javier Read de Alaniz, and Rachel A. Segalman. Macromolecules, 2022, 55 (13), 5723–5732. DOI: 10.1021/acs.macromol.2c00329
193. “Impact of Side Chain Chemistry on Lithium Transport in Mixed Ion–Electron-Conducting Polymers.” Gordon Pace, Oscar Nordness, Kareem Asham, Raphaële J. Clément, and Rachel A. Segalman. Chemistry of Materials, 2022 34 (10), 4672-4681. DOI: 10.1021/acs.chemmater.2c00592
192. “Ionic Tunability of Conjugated Polyelectrolyte Solutions.” Scott P. O. Danielsen, Brittany J. Thompson, Glenn H. Fredrickson, Thuc-Quyen Nguyen, Guillermo C. Bazan, and Rachel A. Segalman. Macromolecules, 55 (9), 3437-3448. DOI: 10.1021/acs.macromol.2c00178
191. “Sequence Modulates Polypeptoid Hydration Water Structure and Dynamics.” Sally Jiao, Daniela M. Rivera Mirabal, Audra J. DeStefano, Rachel A. Segalman, Songi Han, and M. Scott Shell. Biomacromolecules 2022, 23 (4), 1745-1756. DOI: 10.1021/acs.biomac.1c01687
190. “Enhancing the Ionic Conductivity of Poly(3,4-propylenedioxythiophenes) with Oligoether Side Chains for Use as Conductive Cathode Binders in Lithium-Ion Batteries.” Pratyusha Das, Rodrigo Elizalde-Segovia, Billal Zayat, Charlene Z. Salamat, Gordon Pace, Kuan Zhai, Rebecca C. Vincent, Bruce S. Dunn, Rachel A. Segalman, Sarah H. Tolbert, Sri R. Narayan, and Barry C. Thompson. Chemistry of Materials 2022, 34 (6), 2672-2686. DOI: 10.1021/acs.chemmater.1c03971
189. “Polycation radius of gyration in a polymeric ionic liquid (PIL): the PIL melt is not a theta solvent.” Wong LN, Jones SD, Wood K, de Campo L, Darwish T, Moir M, Li H, Segalman RA, Warr GG, Atkin R. Phys Chem Chem Phys. 2022. DOI: 10.1039/d1cp05354j
188. “Discrete, Shallow Doping of Semiconductors via Cylinder-Forming Block Copolymer Self-Assembly.” Y. Y. Zhang, S. P. O. Danielsen, B. C. Popere, A. T. Heitsch, M. Q. Li, P. Trefonas, R. A. Segalman & R. Katsumata. Macromol Mater Eng,2022, DOI: 10.1002/mame.202200155.
187. “Effects of Amphiphilic Polypeptoid Side Chains on Polymer Surface Chemistry and Hydrophilicity.” Mikayla E. Barry, Pinar Aydogan Gokturk, Audra J. DeStefano, Amanda K. Leonardi, Christopher K. Ober, Ethan J. Crumlin, and Rachel A. Segalman. ACS Applied Materials & Interfaces 2022, 14 (5), 7340-7349. DOI: 10.1021/acsami.1c22683
186. “Role of Electron-Deficient Imidazoles in Ion Transport and Conductivity in Solid-State Polymer Electrolytes.” Andrei Nikolaev, Peter M. Richardson, Shuyi Xie, Luana Canzian Llanes, Seamus D. Jones, Oscar Nordness, Hengbin Wang, Guillermo C. Bazan, Rachel A. Segalman, Raphaële J. Clément, and Javier Read de Alaniz. Macromolecules 2022, 55 (3), 971-977. DOI: 10.1021/acs.macromol.1c01979
185. “Confinement Promotes Hydrogen Bond Network Formation and Grotthuss Proton Hopping in Ion-Conducting Block Copolymers.” Sheetal K. Jain, Dakota Rawlings, Ségolène Antoine, Rachel A. Segalman, and Songi Han. Macromolecules 2022, 55 (2), 615-622. DOI: 10.1021/acs.macromol.1c01808
184. “Chain Stiffness of Donor–Acceptor Conjugated Polymers in Solution.” Scott P. O. Danielsen, Colin R. Bridges, and Rachel A. Segalman. Macromolecules 2022, 55 (2), 437-449. DOI: 10.1021/acs.macromol.1c02229
183. “Design of Polymeric Zwitterionic Solid Electrolytes with Superionic Lithium Transport.” Seamus D. Jones, Howie Nguyen, Peter M. Richardson, Yan-Qiao Chen, Kira E. Wyckoff, Craig J. Hawker, Raphaële J. Clément, Glenn H. Fredrickson, and Rachel A. Segalman. ACS Central Science 2022, 8 (2), 169-175. DOI: 10.1021/acscentsci.1c01260
182. “Optimum in ligand density for conductivity in polymer electrolytes.” N. S. Schauser, P. M. Richardson, A. Nikolaev, P. Cooke, G. A. Kliegle, E. M. Susca, K. Johnson, H. Wang, J. Read de Alaniz, R. Clément, R. A. Segalman. Molecular Systems Design & Engineering 2021, 6, 1025-1038. DOI: 10.1039/D1ME00089F
181. “Dopamine-Mediated Polymer Coating Facilitates Area-Selective Atomic Layer Deposition.” Hellen Papananou, Reika Katsumata, Zachary Neary, Rubayn Goh, Xiangxi Meng, Ratchana Limary, and Rachel A. Segalman. ACS Applied Polymer Materials 2021, 3 (10), 4924-4931. DOI: 10.1021/acsapm.1c00692
180. “Where Biology and Traditional Polymers Meet: The Potential of Associating Sequence-Defined Polymers for Materials Science.” Audra J. DeStefano, Rachel A. Segalman, and Emily C. Davidson. JACS Au 2021, 1 (10), 1556-1571. DOI: 10.1021/jacsau.1c00297
179. “Ion Pair Uptake in Ion Gel Devices Based on Organic Mixed Ionic–Electronic Conductors.” T. J. Quill, G. LeCroy, A. Melianas, D. Rawlings, Q. Thiburce, R. Sheelamanthula, C. Cheng, Y. Tuchman, S. T. Keene, I. McCulloch, R. A. Segalman, M. L. Chabinyc, and A. Salleo. Advanced Functional Materials 2021, 2104301. DOI: 10.1002/adfm.202104301
178. “Interfacial Nanostructure and Friction of a Polymeric Ionic Liquid-Ionic Liquid Mixture as a Function of Potential at Au(111) Electrode Interface.” Hua Li, Yunxiao Zhang, Seamus Jones, Rachel Segalman, Gregory G. Warr, and Rob Atkin. Journal of Colloid and Interface Science 2021, 606 (2), 1170-1178. DOI: 10.1016/j.jcis.2021.08.067
177. “Li+ and Oxidant Addition To Control Ionic and Electronic Conduction in Ionic Liquid-Functionalized Conjugated Polymers.” Dakota Rawlings, Dongwook Lee, Jeongmin Kim, Ioan-Bogdan Magdău, Gordon Pace, Peter M. Richardson, Elayne M. Thomas, Scott P. O. Danielsen, Sarah H. Tolbert, Thomas F. Miller, Ram Seshadri, and Rachel A. Segalman. Chemistry of Materials 2021, 33 (16), 6464-6474. DOI: 10.1021/acs.chemmater.1c01811
176. “Aqueous Formulation of Concentrated Semiconductive Fluid Using Polyelectrolyte Coacervation.” My Linh Le, Dakota Rawlings, Scott P. O. Danielsen, Rhys M. Kennard, Michael L. Chabinyc, and Rachel A. Segalman. ACS Macro Letters 2021, 0, 10. DOI: 10.1021/acsmacrolett.1c00354
175. “Non-intuitive Trends in Flory–Huggins Interaction Parameters in Polyether-Based Polymers.” Ségolène Antoine, Zhishuai Geng, Everett S. Zofchak, Malgorzata Chwatko, Glenn H. Fredrickson, Venkat Ganesan, Craig J. Hawker, Nathaniel A. Lynd, and Rachel A. Segalman. Macromolecules 2021, 54 (14), 6670-6677. DOI: 10.1021/acs.macromol.1c00134
174. “Amphiphilic Nitroxide-Bearing Siloxane-Based Block Copolymer Coatings for Enhanced Marine Fouling Release.” Amanda Leonardi, Aria C. Zhang, Nilay Düzen, Nick Aldred, John A. Finlay, Jessica L. Clarke, Anthony S. Clare, Rachel A. Segalman, and Christopher K. Ober. ACS Applied Materials & Interfaces 2021, 13 (24), 28790-28801. DOI: 10.1021/acsami.1c05266
173. “Tuning the Double Gyroid Phase Window in Block Copolymers via Polymer Chain Conformation Near the Interface.” Beihang Yu, Ruipeng Li, and Rachel A. Segalman. Macromolecules 2021, 54 (12), 5388-5396. DOI: 10.1021/acs.macromol.1c00048
172. “Postdeposition Processing Influences the Relative Contributions of Electronic and Ionic Seebeck Effects in the Thermoelectric Response of Conducting Polymers.” Melda Sezen-Edmonds, Anne M. Glaudell, William B. Chang, Rachel A. Segalman, Michael L. Chabinyc, and Yueh-Lin Loo. The Journal of Physical Chemistry C 2021, 125 (22), 12289-12296. DOI: 10.1021/acs.jpcc.1c01399
171. “Quantifying Polypeptoid Conformational Landscapes through Integrated Experiment and Simulation.” Sally Jiao, Audra DeStefano, Jacob I. Monroe, Mikayla Barry, Nicholas Sherck, Thomas Casey, Rachel A. Segalman, Songi Han, and M. Scott Shell. Macromolecules 2021, 54 (11), 5011-5021. DOI: 10.1021/acs.macromol.1c00550
170. “Electronic, Ionic, and Mixed Conduction in Polymeric Systems.” Elayne M. Thomas, Phong H. Nguyen, Seamus D. Jones, Michael L. Chabinyc, and Rachel A. Segalman. Annual Reviews of Materials Research 2021, 51 (1), 1-20. DOI: 10.1146/annurev-matsci-080619-110405
169. “Redox-Active Polymeric Ionic Liquids with Pendant N-Substituted Phenothiazine.” Saejin Oh, Andrei Nikolaev, Kan Tagami, Thi Tran, Dongwook Lee, Sanjoy Mukherjee, Rachel A. Segalman, Songi Han, Javier Read de Alaniz, and Michael L. Chabinyc. ACS Applied Materials & Interfaces 2021, 13 (4), 5319-5326. DOI: 10.1021/acsami.0c20462
168. “Versatile Synthetic Platform for Polymer Membrane Libraries Using Functional Networks.” Joshua D. Moon, Rahul Sujanani, Zhishuai Geng, Benny D. Freeman, Rachel A. Segalman, and Craig J. Hawker. Macromolecules 2021, 54 (2), 866-873. DOI: 10.1021/acs.macromol.0c02414
167. “Light-Switchable and Self-Healable Polymer Electrolytes Based on Dynamic Diarylethene and Metal-Ion Coordination.” H. Nie, N. S. Schauser, J. L. Self, T. Tabassum, S. Oh, Z. Geng, S. D. Jones, M. S. Zayas, V. G. Reynolds, M. L. Chabinyc, C. J. Hawker, S. Han, C. M. Bates, R. A. Segalman, and J. Read de Alaniz. Journal of the American Chemical Society 2021, 143 (3), 1562-1569. DOI: 10.1021/jacs.0c11894
166. “Glass Transition Temperature and Ion Binding Determine Conductivity and Lithium–Ion Transport in Polymer Electrolytes.” Nicole S. Schauser, Andrei Nikolaev, Peter M. Richardson, Shuyi Xie, Keith Johnson, Ethan M. Susca, Hengbin Wang, Ram Seshadri, Raphaële J. Clément, Javier Read de Alaniz, and Rachel A. Segalman. ACS Macro Letters 2021, 10 (1), 104-109. DOI: 10.1021/acsmacrolett.0c00788
165. “The Role of Polymer–Ion Interaction Strength on the Viscoelasticity and Conductivity of Solvent-Free Polymer Electrolytes.” Seamus D. Jones, Nicole S. Schauser, Glenn H. Fredrickson, and Rachel A. Segalman. Macromolecules 2020, 53 (23), 10574-10581. DOI: 10.1021/acs.macromol.0c02233
164. “End-to-End Distance Probability Distributions of Dilute Poly(ethylene oxide) in Aqueous Solution.” N. Sherck, T. Webber, D. R. Brown, T. Keller, M. Barry, A. DeStefano, S. Jiao, R. A. Segalman, G. H. Fredrickson, M. S. Shell, and S. Han. JACS 2020, 142 (46), 19631-19641. DOI: 10.1021/jacs.0c08709
163. “Effects of Counter‐Ion Size on Delocalization of Carriers and Stability of Doped Semiconducting Polymers.” E. M. Thomas, K. A. Peterson, A. H. Balzer, D. Rawlings, N. Stingelin, R. A. Segalman, and M. L. Chabinyc. Adv. Electron. Mater. 2020, 2000595. DOI: 10.1002/aelm.202000595
162. “Dihexyl-Substituted Poly(3,4-Propylenedioxythiophene) as a Dual Ionic and Electronic Conductive Cathode Binder for Lithium-Ion Batteries.” P. Das, B. Zayat, Q. Wei, C. Z. Salamat, I.-B. Magdău, R. Elizalde-Segovia, D. Rawlings, D. Lee, G. Pace, A. Irshad, L. Ye, A. Schmitt, R. A. Segalman, T. F. Miller, S. H. Tolbert, B. S. Dunn, S. R. Narayan, and B. C. Thompson. Chemistry of Materials, 2020, 32 (21), 9176-9189.
DOI: 10.1021/acs.chemmater.0c02601
161. “Directly Probing Polymer Thin Film Chemistry and Counterion Influence on Water Sorption.” Pinar Aydogan Gokturk, Mikayla Barry, Rachel Segalman, and Ethan J. Crumlin. ACS Applied Polymer Materials, 2020, 2 (11), 4752-4761.
DOI: 10.1021/acsapm.0c00756
160. “Can Self-Assembly Address the Permeability/Selectivity Trade-Offs in Polymer Membranes?” Joshua D. Moon, Benny D. Freeman, Craig J. Hawker, and Rachel A. Segalman. Macromolecules 2020, 53, 14, 5649-5654. DOI: 10.1021/acs.macromol.0c01111
159. “Role of Side-Chain Architecture in Poly(ethylene oxide)-Based Copolymers.” Z. Geng, N. S. Schauser, J. Lee, R. Perez Schmeller, S. M. Barbon, R. A. Segalman, N. A. Lynd, and C. J. Hawker. Macromolecules 2020, 53, 12, 4960–4967. DOI: 10.1021/acs.macromol.0c01116
158. “Insensitivity of Sterically Defined Helical Chain Conformations to Solvent Quality in Dilute Solution.” B. Yu, S. P. O. Danielsen, K. Yang, R. Ho, L. M. Walker, and R. A. Segalman. ACS Macro Lett. 2020, 9, 6, 849–854. DOI: 10.1021/acsmacrolett.0c00293
157. “On the growth, structure and dynamics of P3EHT crystals.” G. C. Faria, D. T. Duong, G. Paro da Cunha, P. Selter, L. A. Strassø, E. C. Davidson, R. A. Segalman, M. R. Hansen, E. R. de Azevedo, and A. Salleo. Journal of Materials Chemistry C 2020, 8, 8155-8170. DOI: 10.1039/D0TC00704H
156. “In-situ resonant band engineering of solution-processed semiconductors generates high performance n-type thermoelectric nano-inks,” A. Sahu, B. Russ, M. Liu, F. Yang, E. W. Zaia, M. P. Gordon, J. D. Forster, Y. Zhang, M. C. Scott, K. A. Persson, N. E. Coates, R. A. Segalman, and J. J. Urban. Nature Communications 2020, 11(1), 1-12.
DOI: 10.1038/s41467-020-15933-2
155. “Monomer Sequence Effects on Interfacial Width and Mixing in Self-Assembled Diblock Copolymers,” A. L. Patterson, B. Yu, S. P. O. Danielsen, E. C. Davidson, G. H. Fredrickson, and R. A. Segalman. Macromolecules 2020, 53, 9, 3262–3272. DOI: 10.1021/acs.macromol.9b02426
154. “The Role of Backbone Polarity on Aggregation and Conduction of Ions in Polymer Electrolytes,” N. S. Schauser, D. J. Grzetic, T. Tabassum, G. A. Kliegle, M. L. Le, E. M. Susca, S. Antoine, T. J. Keller, K. T. Delaney, S. Han, R. Seshadri, G. H. Fredrickson, and R. A. Segalman. Journal of the American Chemical Society, 2020, 142 (15), 7055-7065. DOI: 10.1021/jacs.0c00587
153. “Light‐Controllable Ionic Conductivity in a Polymeric Ionic Liquid,” H. Nie, N. S. Schauser, N. D. Dolinski, J. Hu, C. J. Hawker, R. A. Segalman, J. Read de Alaniz. Angew. Chem. Int. Ed. 2020, 59, 5123. DOI: https://doi.org/10.1002/anie.201912921
152. “Influence of pore morphology on the diffusion of water in triblock copolymer membranes,” D. Aryal, M.P. Howard, R. Samanta, S. Antoine, R. A. Segalman, T. M. Truskett, and V. Ganesan. The Journal of Chemical Physics 2020, 152, 1, 014904. DOI: 10.1063/1.5128119
151. “Controlling the Doping Mechanism in Poly(3-hexylthiophene) Thin-Film Transistors with Polymeric Ionic Liquid Dielectrics,” D. Rawlings, E. M. Thomas, R. A. Segalman, and M. L. Chabinyc. Chem. Mater. 2019. 31, 21, 8820-8829.
DOI: 10.1021/acs.chemmater.9b02803.
150. “Absence of Electrostatic Rigidity in Conjugated Polyelectrolytes with Pendant Charges,” S. P. O. Danielsen, E. C. Davidson, G. H. Fredrickson, and R. A. Segalman, ACS Macro Lett., 2019. 8, 1147-1152. DOI: 10.1021/acsmacrolett.9b00551
149. “Rapid and Selective Deposition of Patterned Thin Films on Heterogeneous Substrates via Spin Coating,” Y. Y. Zhang, C. A. D'ambra, R. Katsumata, R. L. Burns, M. H. Somervell, R. A. Segalman, C. J. Hawker, and C. M. Bates, ACS Applied Materials & Interfaces, 2019. 11(23): p. 21177-21183. DOI: 10.1021/acsami.9b05190
148. “Selective spin-on deposition of polymers on heterogeneous surfaces.” Y. Y. Zhang, C. D'Ambra, R. Katsumata, R. A. Segalman, C. J. Hawker & C. M. Bates, Proc Spie, 2019, 10960, DOI: 10.1117/12.2515666
14. 7“Effects of Helical Chain Shape on Lamellae-Forming Block Copolymer Self-Assembly,” B. Yu, S. P. O. Danielsen, A. L. Patterson, E. C. Davidson, and R. A. Segalman. Macromolecules, 2019, 52, 6, 2560-2568. DOI: 10.1021/acs.macromol.9b00211
146. “Multivalent Ion Conduction in Solid Polymer Systems,” N.S. Schauser, R. Seshadri, R.A. Segalman. Molecular Systems Design & Engineering, 2019, 4, 263-279. DOI: 10.1039/c8me00096d
145. “The Role of Hydrogen Bonding in Peptoid-Based Marine Antifouling Coatings,” M. E. Barry, E. C. Davidson, C. Zhang, A. L. Patterson, B. Yu, A. K. Leonardi, N. Duzen, K. Malaviya, J. L. Clarke, J. A. Finlay, A. S. Clare, Z. Chen, C. K. Ober, R. A. Segalman. Macromolecules, 2019, 52, 3, 1287–1295. DOI: 10.1021/acs.macromol.8b02390
144. “Sequence Effects on Block Copolymer Self-Assembly through Tuning Chain Conformation and Segregation Strength Utilizing Sequence-Defined Polypeptoids,” A. L. Patterson, S. P. O. Danielsen, B. Yu, E. C. Davidson, G. H. Fredrickson, R. A. Segalman. Macromolecules, 2019, 52, 3, 1277–1286. DOI: 10.1021/acs.macromol.8b02298
143. “Nonaggregating Doped Polymers Based on Poly(3,4-Propylenedioxythiophene),” A. Mazaheripour, E. M. Thomas, R. A. Segalman, and M. L. Chabinyc. Macromolecules, 2019. 52, 5, 2203-2213. DOI: 10.1021/acs.macromol.8b02389.
142. “Complexation of a Conjugated Polyelectrolyte and Impact on Optoelectronic Properties,” S. P. O. Danielsen, T.-Q. Nguyen, G. H. Fredrickson, R. A. Segalman. ACS Macro Letters, 2019, 8, 88-94. DOI: 10.1021/acsmacrolett.8b00924
141. “Branched Side Chains Govern Counterion Position and Doping Mechanism in Conjugated Polythiophenes,” E. M. Thomas, E. C. Davidson, R. Katsumata, R. A. Segalman, M. L. Chabinyc. ACS Macro Lett., 2018, 7, 1492−1497. DOI: 10.1021/acsmacrolett.8b00778
140. “Effects of Side Chain Branch Point on Self Assembly, Structure, and Electronic Properties of High Mobility Semiconducting Polymers,” C. R. Bridges, M. J. Ford, E. M. Thomas, C. Gomez, G. C. Bazan, R. A. Segalman. Macromolecules, 2018, 51 (21), 8597-8604. DOI: 10.1021/acs.macromol.8b01906
139. “X-Ray Scattering Reveals Ion-Induced Microstructural Changes During Electrochemical Gating of Poly(3-Hexylthiophene),” E. M. Thomas, M. A. Brady, H. Nakayama, B. C. Popere, R. A. Segalman, M. L. Chabinyc. Adv. Funct. Mater., 2018, 1803687. DOI: 10.1002/adfm.201803687
138. "Unraveling the Effect of Conformational and Electronic Disorder in the Charge Transport Processes of Semiconducting Polymers", Annabel R. Chew, Raja Ghosh, Viktoria Pakhnyu, Jonathan Onorato, Emily C. Davidson, Rachel A. Segalman, Christine K. Luscombe, Frank C. Spano, Alberto Salleo. Advanced Functional Materials, 2018, 1804142. DOI: 10.1002/adfm.201804142
137. "Decoupling Bulk Mechanics and Mono- and Multivalent Ion Transport in Polymers Based on Metal–Ligand Coordination", Nicole S. Schauser, Gabriel E. Sanoja, Joshua M. Bartels, Sheetal K. Jain, Jerry G. Hu, Songi Han, Lynn M. Walker, Matthew E. Helgeson, Ram Seshadri, Rachel A. Segalman. Chemistry of Materials, 2018, 30 (16), 5759-5769
DOI: 10.1021/acs.chemmater.8b02633
136. "Photocrosslinking polymeric ionic liquids via anthracene cycloaddition for organic electronics", Bhooshan C. Popere, Gabriel E. Sanoja, Elayne M. Thomas, Nicole S. Schauser, Seamus D. Jones, Joshua M. Bartels, Matthew E. Helgeson, Michael L. Chabinyc, Rachel A. Segalman. Journal of Materials Chemistry C, 2018, 6, 8762-8769.
DOI: 10.1039/C8TC02561D
135."Mussel-Inspired Strategy for Stabilizing Ultrathin Polymer Films and Its Application to Spin-On Doping of Semiconductors", R. Katsumata, R. Limary, Y. Zhang, B. C. Popere, A. T. Heitsch, M. Li, P. Trefonas, R. A. Segalman. Chemistry of Materials, 2018, 30 (15), 5285-5292.
DOI: 10.1021/acs.chemmater.8b02027
134. "Tailoring the Seebeck Coefficient of PEDOT:PSS by Controlling Ion Stoichiometry in Ionic Liquid Additives", A. Mazaheripour, S. Majumdar, D. Hanemann-Rawlings, E. M. Thomas, C. McGuiness, L. d'Alencon, M. L. Chabinyc, R. A. Segalman. Chemistry of Materials, 2018, 30 (14), 4816-4822.
DOI: 10.1021/acs.chemmater.8b02114
133."Thermoreversible Hyaluronic Acid‐PNIPAAm Hydrogel Systems for 3D Stem Cell Culture," B. L. Ekerdt, C. M. Fuentes, Y. Lei, M. M. Adil, A. Ramasubramanian, R. A. Segalman, D. V. Schaffer, Advanced Healthcare Materials, 2018. DOI: 10.1002/adhm.201800225
132. "Role of Disorder Induced by Doping on the Thermoelectric Properties of Semiconducting Polymers", E. M. Thomas, B. C. Popere, H. Fang, M. L. Chabinyc, R. A. Segalman. Chemistry of Materials, 2018, 30 (9), 2965-2972.
DOI: 10.1021/acs.chemmater.8b00394
131. "Impact of Helical Chain Shape in Sequence-Defined Polymers on Polypeptoid Block Copolymer Self-Assembly," E. C. Davidson, A. Rosales, A. L. Patterson, B. Yu, R. Zuckermann, R. A. Segalman. Macromolecules, 2018, 51 (5), 2089–2098.
DOI: 10.1021/acs.macromol.8b00055
130. "Ion Transport in Dynamic Polymer Networks Based on Metal–Ligand Coordination: Effect of Cross-Linker Concentration" G. E. Sanoja, N. S. Schauser, J. M. Bartels, C. M. Evans, M. E. Helgeson, R. Seshadri, R. A. Segalman. Macromolecules, 2018, 51 (5), 2017-2026.
DOI: 10.1021/acs.macromol.7b02141
129. "Mixed Conductive Soft Solids by Electrostatically Driven Network Formation of a Conjugated Polyelectrolyte" S. P. O. Danielsen, G. E. Sanoja, S. R. McCuskey, B. Hammouda, G. C. Bazan, G. H. Fredrickson, R. A. Segalman. Chemistry of Materials, 2018, 30 (4), 1417-1426.
DOI: 10.1021/acs.chemmater.7b05303
128. "Temperature-Dependence of Persistence Length Affects Phenomenological Descriptions of Aligning Interactions in Nematic Semiconducting Polymers," J. Martin, E. C. Davidson, C. Greco, W. Xu, J. H. Bannock, A. Agirre, J. de Mello, R. A. Segalman, N. Stingelin, K. Ch. Daoulas. Chemistry of Materials, 2018, 30 (3), 748-761.
DOI: 10.1021/acs.chemmater.7b04194
127. "Decoupling Mechanical and Conductive Dynamics of Polymeric Ionic Liquids via a Trivalent Anion Additive," J. Bartels. G. E. Sanoja, C. M. Evans, R. A. Segalman, M. E. Helgeson. Macromolecules, 2017, 50, 8979-8986.
DOI: 10.1021/acs.macromol.7b01351
126. "Thermal Control of Confined Crystallization within P3EHT Block Copolymer Microdomains," E. C. Davidson, R. A. Segalman. Macromolecules, 2017, 50 (20), 8097-8105.
DOI: 10.1021/acs.macromol.7b01616
125. "Confined Crystallization within Cylindrical P3EHT Block Copolymer Microdomains," E. C. Davidson, R. A. Segalman. Macromolecules, 2017, 50 (16), 6128-6136.
DOI: 10.1021/acs.macromol.7b01323
124. "Tuning the optoelectronic properties of P3EHT block copolymers by surface modification," International Journal of Nanotechnology, 2017. DOI: 10.1504/IJNT.2017.082481
123."Isothermal Crystallization Kinetics and Time–Temperature–Transformation of the Conjugated Polymer: Poly(3-(2′-ethyl)hexylthiophene)," L. Yu, E. Davidson, A. Sharma, M. R. Andersson, R. Segalman, C. Müller. Chemistry of Materials, 2017, 29 (13), 5654-5662.
DOI: 10.1021/acs.chemmater.7b01393
122. "Oligopeptide-Modified Hydrophobic and Hydrophilic Polymers as Antifouling Coatings," D. R. Calabrese, B. M. Wenning, H. Buss, J. A. Finlay, A. S. Clare, D. Fischer, R. A. Segalman, C. K. Ober. Green Materials, 2017, 5, 1, 1-42.
DOI: 10.1680/jgrma.17.00006
121. "Molecular Considerations for Mesophase Interaction and Alignment of Lyotropic Liquid Crystalline Semiconducting Polymers," C. R. Bridges, M. J. Ford, G. C. Bazan, R. A. Segalman. ACS Macro Letters, 2017, 6, 619-624.
DOI: 10.1021/acsmacrolett.7b00273
120. "Role of Backbone Chemistry and Monomer Sequence in Amphiphilic Oligopeptide- and Oligopeptoid-Functionalized PDMS- and PEO-Based Block Copolymers for Marine Antifouling and Fouling Release Coatings," A. L. Patterson, B. Wenning, G. Rizis, D. R. Calabrese, J. A. Finlay, S. C. Franco, R. N. Zuckermann, A. S. Clare, E. J. Kramer, C. K. Ober, R. A. Segalman. Macromolecules, 2017, 50, 7, 2656–2667. DOI: 10.1021/acs.macromol.6b02505
119. “Formation and Structure of Lyotropic Liquid Crystalline Mesophases in Donor-Acceptor Semiconducting Polymers,” C. R. Bridges, M. J. Ford, B. C. Popere, G. C. Bazan, R. A. Segalman. Macromolecules, 2016, 49, 19, 7220–7229. DOI: 10.1021/acs.macromol.6b01650
118. “Bottom-up design of de novo thermoelectric hybrid materials using chalcogenide resurfacing.” A. Sahu, B. Russ, N. C. Su, R. A. Segalman, J. J. Urban*, Journal of Materials Chemistry A, 2017, 5 (7) 3346-3357.
117. “Large-Scale Integration of Flexible Materials into Rolled and Corrugated Thermoelectric Modules,” H. Fang, B.C. Popere, E. M. Thomas, C.-K. Mai, W. B. Chang, G. C. Bazan, M. L. Chabinyc, R. A. Segalman. J. Appl. Polym. Sci., 2016, 44208. DOI: 10.1002/app.44208
116. “Anisotropic Thermal Transport in Thermoelectric Composites of Conjugated Polyelectrolytes/Single-Walled Carbon Nanotubes.” C-K Mai, J. Liu, C.M. Evans, R. A. Segalman, G.C. Bazan*, Macromolecules, 2016, 13, pp 4957-4963.
115.“Organic thermoelectric materials for energy harvesting and temperature control,” B. Russ, A. Glaudell, J.J. Urban, M.L. Chabinyc, R.A. Segalman. Nature Reviews Materials, 2016, 1, 16050.
114. “Role of Tethered Ion Placement on Polymerized Ionic Liquid Structure and Conductivity: Pendant versus Backbone Charge Placement,” C. M. Evans, C.R. Bridges, G.E. Sonoja, J. Bartels, R. A. Segalman. ACS Macro Letters, 2016, 5, 925-930.
113. “Structure-Conductivity Relationships of Block Copolymer Membranes Based on Hydrated Protic Polymerized Ionic Liquids: Effect of Domain Spacing,” G.E. Sanoja, B.C. Popere, B.S. Beckingham, C.M. Evans, N.A. Lynd, R.A. Segalman. Macromolecules, 2016, 49(6), 2216–2223.
112. “High Mobility Organic Field-Effect Transistors from Majority Insulator Blends,” M. J. Ford, M. Wang, S. N. Patel, H. Phan, R. A. Segalman, T.-Q. Nguyen, G. C. Bazan. Chemistry of Materials, 2016, 28(5), 1256–1260.
111. "Electrochemical Effects in Thermoelectric Polymers," W.B. Chang, H. Fang, J. Liu, C.M. Evans, B. Russ, B.C. Popere, S.N. Patel, M.L. Chabinyc, R.A. Segalman, Macro Letters, 2016, 5(4), 455-459.
110. "Tethered Tertiary Amines as Solid-state n-type Dopants for Solution-processable Organic Semiconductors," B. Russ, M.J. Robb, B.C. Popere, E.E. Perry, C-K. Mai, S.L. Fronk, S.N. Patel, T.E. Mates, G.C. Bazan, J.J. Urban, M.L. Chabinyc, C.J. Hawker, R.A. Segalman, Chemical Science, 2016, 7, 1914-1919. DOI: 10.1039/C5SC04217H
109. "Anhydrous Proton Transport in Polymerized Ionic Liquid Block Copolymers: Roles of Block Length, Ionic Content, and Confinement," C.M. Evans, G.E. Sanoja, B.C. Popere, R.A. Segalman, Macromolecules, 2016, 49(1), 395-404. DOI: 10.1021/acs.macromol.5b02202
108. "Harvesting Waste Heat in Unipolar Ion Conducting Polymers," W.B. Chang, C.M. Evans, B.C. Popere, B.M. Russ, J. Liu, J. Newman, R.A. Segalman., Macro Letters, 2016, 5 (1), 94-98. DOI: 10.1021/acsmacrolett.5b00829
107. "Surface Structure and Hydration of Sequence-Specific Amphiphilic Polypeptoids for Antifouling/Fouling Release Applications," C. Leng, H.G. Buss, R.A. Segalman, Z. Chen, Langmuir, 2015, 31(34), 9306-9311. DOI: 10.1021/acs.langmuir.5b01440
106. "Large-Area, Nanometer-Scale Discrete Doping of Semiconductors via Block Copolymer Self-Assembly," B.C. Popere, B. Russ, A.T. Heitsch, P. Trefonas, R.A. Segalman, Advanced Materials Interfaces, 2015. DOI: 10.1002/admi.201500421
105. "Confined Crystallization in Lamellae Forming Poly(3-(2'-ethyl)hexylthiophene) (P3EHT) Block Copolymers," E.C. Davidson, B.S. Beckingham, V. Ho, R.A. Segalman, J. of Polymer Science Part B: Polymer Physics, 2015. DOI: 10.1002/polb.23904
104. “In Memory of Professor Edward J. Kramer.” R.J. Composto, K.I. Winey and R.A. Segalman, E.W. Meijer, Journal of Polymer Science, Part A Polymer Chemistry 2016; 54(2), pp227.
103. “Electrical Properties of Doped Conjugated Polyelectrolytes with Modulated Density of the Ionic Functionalities,” C.-K. Mai, T. Arai, X. Liu, S.L. Fronk, G.M. Su, R.A. Segalman, M.L. Chabinyc and G.C. Bazan Chemical Communications, 2015; 51, 17607-17610.
102. "Varying the Ionic Functionalities of Conjugated Polyelectrolytes Leads to both p- and n-type Carbon Nanotube Composites for Flexible Thermoelectrics," C.K. Mai, B. Russ, S. Fronk, N. Hu, M.B. Chan-Park, JJ. Urban, R.A. Segalman, M.L. Chabinyc, G.C. Bazan, Energy and Environmental Science, 2015, 8, 2341-2346.
101. "Role of Side-Chain Branching on Thin-Film Structure and Electronic Properties of Polythiophenes," S. Himmelberger, D.T. Duong, J.E. Northrup, J. Rivnay, F.P.V. Koch, B.S. Beckingham, N. Stingelin, R.A. Segalman, S.C.B. Mannsfeld, A. Salleo, Advanced Functional Materials, 2015, 25(17), 2616-2624.
100. "Improving the Gas Barrier Properties of Nafion via Thermal Annealing: Evidence for Diffusion through Hydrophilic Channels and Matrix," C.M. Evans, M.R. Singh, N.A. Lynd, R.A. Segalman, Macromolecules, 2015, 48(10), 3303-3309.
99. "Gold Nanocrystal Arrays as a Macroscopic Platform for Molecular Junction Thermoelectrics," W.B. Chang, B. Russ, V. Ho, J.J. Urban, R.A. Segalman, Physical Chemistry Chemical Physics, 2015.
98. "Thermal Conductivity and Elastic Constants of PEDOT:PSS with High Electrical Conductivity," J. Liu, X. Wang, D. Li, N.E. Coates, R.A. Segalman, D.G. Cahill, Macromolecules, 2015.
97. "Enhanced Water Vapor Blocking in Transparent Hybrid Polymer-Nanocrystal Films," E.S. Cho, C.M. Evans, E.C. Davidson, M.L. Hoarfrost, M.A. Modestino, R.A. Segalman, J.J. Urban, Macro Letters, 2015, 4 (1), 70-74.
96. “Exploring the Potential of Fulvalene Dimetals as Platforms for Molecular Solar Thermal Energy Storage: Computations, Syntheses, Structures, Kinetics, and Catalysis,” K. Borjesson, D. Coso, V. Gray, J. C. Grossman, J. Q. Guan, C. B. Harris, N. Hertkorn, Z. R. Hou, Y. Kanai, D. Lee, J. P. Lomont, A. Majumdar, S. K. Meier, K. Moth-Poulsen, R. L Myrabo, S. C. Nguyen, R. A. Segalman, V. Srinivasan, W. B. Tolman, N. Vinokurov, K.P. C. Vollhardt and T. W. Weidman, Chemistry A. European Journal, 2014; 20(14), 15587-15604.
95."Controlling the Thermoelectric Properties of Thiophene-Derived Single-Molecule Junctions," W.B. Chang, C.K. Mai, M.Kotiuga, J.B. Neaton, G.C. Bazan, R.A. Segalman, Chemistry of Materials, 2014, 26(24), 7229-7235.
94. "Melting Behavior of Poly(3-(2'-ethyl)hexylthiophene)," B.S. Beckingham, V. Ho, R.A. Segalman, Macromolecules, 2014, 47 (23), 8305-8310.
93. “Material requirements for membrane separators in a water-splitting photoelectrochemical cell,” A. Berger, R. A. Segalman and J. S. Newman*, Energy and Environmental Science, 2014; 7(4), 1468-1476.
92. "Formation of a Rigid Amorphous Fraction in Poly(3-(2'-ethyl)hexlthiophene," B.S. Beckingham, V. Ho, R.A. Segalman, Macro Letters, 2014, 3 (7), 684-688.
91. "Sequence of Hydrophobic and Hydrophilic Residues in Amphiphilic Polymer Coatings Affects Surface Structure and Marine Antifouling/Fouling Release Properties," W.van Zoelen, H. Buss, N.C. Ellebracht, N. Lynd, D. Fischer, J. Finlay, S. Hill, M.E. Callow, J.A. Callow, E. Kramer, R.N. Zuckermann, R.A. Segalman,Macro Letters, 2014, 3 (4), 364-368.
90. "Mechanism of Crystallization and Implications for Charge Transport in Poly(3-ethylhexylthiophene) Thin Films," D.T. Duong, V. Ho, Z. Shang, S. Mollinger, S.C.B. Mannsfeld, J. Dacuna, M.F. Tony, R.A. Segalman, A. Salleo, Advanced Functional Materials, 2014, 24 (28), 4515-4521.
89. "Control of thermal and optoelectronic properties in conjugated poly(3-alkylthiophenes)," V. Ho, B.S. Beckingham, H.H. Ng, R.A. Segalman, MRS Communications, 2014, 4 (2), 45-50.
88. "Power Factor Enhancement in Solution-Processed Organic n-Type Thermoelectrics Through Molecular Design," B. Russ, M.J. Robb, F.G. Brunetti, P.L. Miller, E.E. Perry, S.N. Patel, V. Ho, W.B. Chang, J.J. Urban, M.L. Chabinyc, C.J. Hawker, R.A. Segalman, Advanced Materials, 2014. DOI: 10.1002/adma.201306116.
87. "Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator," M.A. Modestino, K.A. Walczak, A. Berger, C.M. Evans, S. Haussener, C. Koval, J.S. Newman, J.W. Agerab, R.A. Segalman, Energy Environ. Sci., 2014, 7, 297-301.
86. "Spatial organization of cell-adhesive ligands for advanced cell culture," B.L. Ekerdt, R.A. Segalman, D.V. Schaffer, Biotechnology Journal, 2013, 8(12), 1411-1423.
85. "Spin-On Organic Polymer Dopants for Silicon," M.L. Hoarfrost, K. Takei, V. Ho, A. Heitsch, P. Trefonas, A. Javey, and R.A. Segalman, J Phys Chem Lett, 2013, 4(21), 3741-3746.
84."Polypeptoids: a model system to study the effect of monomer sequence on polymer properties and self-assembly," A.M. Rosales, R.A. Segalman, R.N. Zuckermann, Soft Matter, 2013, 9, 8400-8414.
83. "Thermal Conductivity of High-Modulus Polymer Fibers," X. Wang, V. Ho, R.A. Segalman, D.G. Cahill, Macromolecules, 2013, 46(12), 4937-4943.
82. "Dynamics of Magnetic Alignment in Rod-Coil Block Copolymers," B.L. McCulloch, G. Portale, W. Bras, J.A. Pople, A. Hexemer, R.A. Segalman, Macromolecules, 2013, 46(11), 4462-4471.
81. "Ultralow Thermal Conductivity in Polycrystalline CdSe Thin Films with Controlled Grain Size," J.P. Feser, E.M. Chan, A. Majumdar, R.A. Segalman, J.J. Urban, Nano Lett, 2013, 13(5), 2122-2127.
80. "Integrated microfluidic test-bed for energy conversion devices," M.A. Modestino, J.W. Ager III, S. Haussener, R. Gomez-Sjoberg, C. Diaz-Botia, R.A. Segalman, Phys. Chem. Chem. Phys., 2013, 15, 7050-7054.
79. "Polymer Chain Shape of Poly(3-alkylthiophenes) in Solution Using Small-Angle Neutron Scattering," B.L. McCulloch, V. Ho, M.L. Hoarfrost, C. Stanley, C. Do, R.A. Segalman, Macromolecules, 2013, 46(5), 1899-1907.
78. "Ionic Conduction in Nanostructured Membranes Based on Polymerized Protic Ionic Liquids," Y. Schneider, M.A. Modestino, B.L. McCulloch, M.L. Hoarfrost, R.W. Hess, R.A. Segalman, Macromolecules, 2013, 46(4), 1543-1548.
77. "Thermoelectric power factor optimization in PEDOT:PSS tellurium nanowire hybrid composites," S.K. Yee, N.E. Coates, A. Majumdar, J.J. Urban, R.A. Segalman, Phys. Chem. Chem. Phys., 2013, 15, 4024-4032.
76. "Effect of Interfacial Properties on Polymer-Nanocrystal Thermoelectric Transport," N.E. Coates, S.K. Yee, B.L. McCulloch, K.C. See, A. Majumdar, R.A. Segalman, J.J. Urban, Advanced Materials, 2013, 25(11), 1629-1633.
75. "Self-assembly and transport limitations in confined Nafion films," M.A. Modestino, D.K. Paul, S. Dishari, S.A. Petrina, F.I. Allen, M.A. Hickner, K. Karan, R.A. Segalman, A.Z. Weber, Macromolecules, 2013, 46(3), 866-873.
74. "Persistence length of polyelectrolytes with precisely located charges," H.K. Murnen, A.M. Rosales, A.V. Dorynin, R.N. Zuckermann, R.A. Segalman, Soft Matter, 2013, 9, 90-98.
73. "Deciphering the Three-Dimensional Morphology of Block Copolymer Thin Films by Transmission Electron Microscopy," F.I. Allen, P. Ercius, M.A. Modestino, R.A. Segalman, N.P. Balsara, A.M. Minor, Micron, 2013, 44, 442-450.
72. "Infrared conductivity of hole accumulation and depletion layers in (Ga,Mn)As- and (Ga,Be)As-based electric field-effect devices," B.C. Chapler, S. Mack, L. Ju, T.W. Elson, B.W. Boudouris, E. Namdas, J.D. Yuen, A.J. Heeger, N. Samarth, M. Di Ventra, R.A. Segalman, D.D. Awschalom, F. Wang, and D.N. Basov , Phys Rev B, 2012, 86, 165302.
71. "Morphology and Thermodynamic Properties of a Copolymer with an Electronically Conducting Block: Poly(3-ethylhexylthiophene)-block-poly(ethylene oxide)," S.N. Patel, A.E. Javier, K.M. Beers, J.A. Pople, V. Ho, R.A. Segalman, N.P. Balsara, Nano Lett, 2012, 12(9), 4901-4906.
70. "Tunable Surface Properties from Sequence Specific Polypeptoid-Polystyrene Block Copolymer Thin Films," W. van Zoelen, R.N. Zuckermann, R.A. Segalman, Macromolecules, 2012, 45(17), 7072-7082.
69. "Structure determination of Pt-coated Au dumbbells via fluctuation X-ray scattering," G. Chen, M.A. Modestino, B.K. Poon, A. Schirotzek, S. Marchesini, R.A. Segalman, A. Hexemer, P.H. Zwart, J. Synchrotron Radiat, 2012, 19, 695-700.
68. "Molecular Solar Thermal (MOST) Energy Storage and Release System," K.M. Poulsen, D. Coso, K. Borjesson, N. Vinokurov, S.K. Meier, K.P.C. Vollhardt, A. Majumdar, R.A. Segalman, Energy and Environmental Science, 2012, 5, 8534-8537.
67. "Tunable Phase Behavior of Polystyrene-Polypeptoid Block Copolymers," A.M. Rosales, B.L. McCulloch, R.N. Zuckermann, R.A. Segalman, Macromolecules, 2012, 45(15), 6027-6035.
66. "Proton Hopping and Long-Range Transport in the Protic Ionic Liquid [Im][TFSI], Probed by Pulsed-Field Gradient NMR and Quasi-Elastic Neutron Scattering," M.L. Hoarfrost, M. Tyagi, R.A. Segalman, J.A. Reimer, J. Phys. Chem. B, 2012, 116(28), 8201-8209.
65. "Impact of Hydrophobic Sequence Patterning on the Coil-to-Globule Transition of Protein-like Polymers," H.K. Murnen, A.R. Khokhlov, P.G. Khalatur, R.A. Segalman, R.N. Zuckermann, Macromolecules, 2012, 45(12), 5229-5236.
64. "Conductivity Scaling Relationships for Nanostructured Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, R.A. Segalman, ACS Macro Letters, 2012, 1, 937-943.
63. "Controlling Nafion Structure and Properties via Wetting Interactions," M.A. Modestino, A. Kusoglu, A. Hexemer, A. Weber, R.A. Segalman, Macromolecules, 2012, 45(11), 4681-4688.
62. "Effect of Confinement on Proton Transport Mechanisms in Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, M.S Tyagi, R.A. Segalman, J.A. Reimer, Macromolecules, 2012, 45(7), 3112-3120.
61. "Determination of the Persistence Length of Helical and Non-Helical Polypeptoids in Solution," A.M. Rosales, H.K. Murnen, S.R. Kline, R.N. Zuckermann, R.A. Segalman, Soft Matter, 2012, 8, 3673-3680.
60. "Sub-second Morphological Changes in Nafion during Water Uptake Detected by Small-Angle X-Ray Scattering," A.Kusoglu, M.A. Modestino, A. Hexemer, R.A. Segalman, A.Z. Weber, ACS Macro Lett, 2012, 1(1), 33-36.
59. "Inverse Rectification in Donor-Acceptor Molecular Heterojunctions," S.K. Yee, J. Sun, P. Darancet, T. Don Tilley, A. Majumdar, J.B. Neaton, R.A. Segalman, ACS Nano, 2011, 5(11), 9256-9263.
58. "Increased Order-Disorder Transition Temperature for a Rod-Coil Block Copolymer in the Presence of a Magnetic Field," B.L. McCulloch, G. Portale, W. Bras, R.A. Segalman, Macromolecules, 2011, 44(19), 7503-7507.
57. “PN junction rectification in electrolyte gated Mg-doped InN,” E. Alarcon-Llado,
M. A. Mayer, B. W. Boudouris, R.A. Segalman*, N. Miller, T. Yamaguchi, K. Wang, Y. Nanishi, E. E. Haller and J.W. Ager*, Applied Physics Letters; 2011; 99 (10), Article 1012106.
56. "Controlling Nanorod Self-Assembly in Polymer Thin-Films," M.A. Modestino, E.R. Chan, A. Hexemer, J.J. Urban, R.A. Segalman, Macromolecules, 2011, 44(18), 7364-7371.
55. "Thermoelectricity in Fullerene-Metal Heterojunctions," S.K. Yee, J.A. Malen, A. Majumdar, R.A. Segalman, Nano Lett, 2011, 11(10), 4089-4094.
54. "Real-Time Observation of Poly(3-alkylthiophene) Crystallization and Correlation with Transient Optoelectronic Properties," B.W. Boudouris, V. Ho, L.H. Jimison, M.F. Toney, A. Salleo, R.A. Segalman, Macromolecules, 2011, 44(17), 6653-6658.
53. "Ionic Conductivity of Nanostructured Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, R.A. Segalman, Macromolecules, 2011, 44(13), 5281-5288.
52. "Poly(3-alkylthiophene) Diblock Copolymers with Ordered Microstructures and Continuous Semiconducting Pathways," V. Ho, B.W. Boudouris, B.L. McCulloch, C.G. Shuttle, M. Burkhardt, M.L. Chabinyc, R.A. Segalman, J. Am. Chem. Soc., 2011, 133 (24), 9270-9273.
51. "Controlling Inelastic Light Scattering Quantum Pathways in Graphene," C.F. Chen, C.H. Park, B.W. Boudouris, J. Horng, B. Geng, C. Girit, A. Zettl, M.F. Crommie, R.A. Segalman, S.G. Louie, F. Wang, Nature, 2011, 471, 617-620.
50. "Hierarchical Self-Assembly of a Biomimetic Diblock Copolypeptoid into Homochiral Superhelices," H.K. Murnen, A.M. Rosales, J.N. Jaworski, R.A. Segalman, R.N. Zuckermann, J. Am. Chem. Soc., 2010, 132 (45), 16112-16119.
49. "Water-Processable Polymer-Nanocrystal Hybrids for Thermoelectrics," K.C. See, J.P. Feser, C.E. Chen, A. Majumdar, J.J. Urban, R.A. Segalman, Nano Lett, 2010, 10(11), 4664-4667.
48. "Tuning Polythiophene Crystallization through Systematic Side Chain Functionalization," V. Ho, B.W. Boudouris, R.A. Segalman, Macromolecules, 2010, 43 (19), 7895-7899.
47. "Liquid Crystalline Orientation of Rod Blocks Within lamellar Nanostructures from Rod-Coil Diblock Copolymers," B.D. Olsen, X. Gu, A. Hexemer, E. Gann, R.A. Segalman, Macromolecules 2010, 43(16), 6531-6534.
46. "Control of Crystallization and Melting Behavior in Sequence Specific Polypeptoids," A.M. Rosales, H.K. Murnen, R.N. Zuckerman, Macromolecules, 2010, 43 (13), 5627-5636.
45. "Effect of an Ionic Liquid Solvent on the Phase Behavior of Block Copolymers," J.M. Virgili, M. Hoarfrost, R.A. Segalman, Macromolecules, 2010, 43(12), 5417-5423.
44. "Fundamentals of Energy Transport, Energy Conversion, and Thermal Properties in Organic-Inorganic Heterojunctions," J.A. Malen, S.K. Yee, A. Majumdar, R.A. Segalman, Chem Phys Lett, 2010, 491, 109-122.
43. "Ionic Liquid Distribution in Ordered Block Copolymer Solutions," J.M. Virgili, A.J. Nedoma, R.A. Segalman, N.P. Balsara, Macromolecules, 2010, 43(8), 3750-3756.
42. "Synthesis and Characterization of Fluorinated Heterofluorene-Containing Donor-Acceptor Systems," K. Geramita, Y.F. Tao, R.A. Segalman, T.D. Tilley, J Org Chem, 2010, 75(6), 1871-1876.
41. "Universal and solution-processable precursor to Bismuth chalcogenide thermoelectrics," R.Y. Wang, J.P. Feser, X.Gu, K.M. Yu, R.A. Segalman, A. Majumdar, D.J. Milliron, J.J. Urban, Chem Mater, 2010, 22(6), 1943-1945.
40. "Block Copolymers for Organic Optoelectronics," R.A. Segalman, B. McCulloch, S. Kirmayer, J.J. Urban, Macromolecules, 42(23), pp 9205-9216, 2009.
39. "Spatial Resolution of a Type II Heterojunction in a Single Bipolar Molecule," C. G. Tao, J. B. Sun, X. W. Zhang, R. Yamachika, D. Wegner, Y. Bahri, G. Samsonidze, S. G. Louie, T. D. Tilly, R.A. Segalman and M. F. Crommie, Nano Lett, 2009, 9(12), 3963-3967.
38. "The Nature of Transport Variations in Molecular Heterojunction Electronics," J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R.A. Segalman and A. Majumdar, Nano Lett, 2009, 9 (10), 3406-3412.
37. "The Relationship Between Morphology and Performance of Donor-Acceptor Rod-Coil Block Copolymer Solar Cells," Y. Tao, B. McCulloch, S. Kim and R.A. Segalman, Soft Matter, 2009, 5, 4219-4230.
36. "Phase Behavior of Polystyrene-block-Poly(2-vinyl pyridine) Copolymers in Selective Ionic Liquid Solvents," J. M. Virgili, A. Hexemer, J. A. Pople, N. Balsara and R.A. Segalman, Macromolecules, 2009, 42, 4604-4613.
35. "Synthesis and Self-Assembly of Poly(diethylhexyloxy-p-phenylenevinylene)-b-poly(methyl methacrylate) Rod-Coil Block Copolymers," C-C Ho, Y-H Lee, C-A Dai, R.A. Segalman and W-F Su, Macromolecules, 2009, 42(12), 4208-4219.
34. "Rheological Properties and the Mechanical Signatures of Phase Transitions in Weakly Segregated Rod-Coil Block Copolymers," B. D. Olsen, N. P. Teclemariam, S. J. Muller, and R.A. Segalman, Soft Matter, 2009, 5(12), 2453-2462.
33. "Identifying the Length Dependence of Orbital Alignment and Contact Coupling in Molecular Heterojunctions," J. A. Malen, P. Doak, K. Baheti, T. D. Tilley, R.A. Segalman and A. Majumdar, Nano Lett 2009, 9(3), 1164-1169.
32. "Near-Surface and Internal Lamellar Structure and Orientation in Thin Films of Rod-Coil Block Copolymers," B. D. Olsen, X. Li, J. Wang and R.A. Segalman, Soft Matter, 2009, 5, 182-192.
31. "Synthesis and Characterizing of 2,7-bis(pentafluorophenylethynyl) hexafluoroheterofluorenes: New Materials with High Electron Affinities," K. Geramita, J. McBee, Y. Tao, R.A. Segalman and T. D. Tilley, Chem Comm, 2008, 41, 5107-5109.
30. "Self-Assembly of Rod-Coil Block Copolymers and their Application in Electroluminescent Devices," Y. Tao, B. Ma and R.A. Segalman, Macromolecules, 2008, 41(19), 7152-7159.
29. "Universalization of the Phase Diagram for a Model Rod-Coil Diblock Copolymer," B. D. Olsen, M. Shah, V. Ganesan and R.A. Segalman, Macromolecules, 2008, 41(18), 6809-6817.
28. "Self-Assembly of Rod-Coil Block Copolymers," B. D. Olsen and R.A. Segalman, Mat Sci Eng R, 2008, 62(2), 37-66.
27. "MATERIALS SCIENCE: Directing Self-Assembly Toward Perfection" R.A. Segalman, Science, 2008, 321, 919.
26. "Enhanced Thermopower in PbSe Nanocrystal Quantum Dot Superlattices," R.Y. Wang, J.P. Feser, J.-S. Lee, D.V. Talapin, R.A. Segalman, A. Majumdar, Nano Lett, 2008, 8(8), 2283-2288.
25. "Square Grains in Asymmetric Rod-Coil Block Copolymers," B.D. Olsen, M.F. Toney, R.A. Segalman, Langmuir, 2008, 24 (5), 1604-1607.
24. "Probing the Chemistry of Molecular Heterojunctions Using Thermoelectricity," K. Baheti, J.A. Malen, P. Doak, P. Reddy, S-Y Jang, T.D. Tilley, A. Majumdar, R.A. Segalman, Nano Lett, 2008, 8(2), 715-719.
23. "Crystalline Structure in Thin Films of DEH-PPV Homopolymer and PPV-b-PI Rod-Coil Block Copolymers," B.D. Olsen, D. Alcazar, V. Krikorian, M.F. Toney, E.L. Thomas, R.A. Segalman, Macromolecules, 2008, 41(1), 58-66.
22. "Hierarchical Nanostructure Control in Rod-Coil Block Copolymers with Magnetic Fields," Y. Tao, H. Zohar, B.D. Olsen, and R.A. Segalman, Nano Lett, 2007, 7(9), 2742-2746.
21. "Non-Lamellar Phases in Asymmetric Rod-Coil Block Copolymers," B.D. Olsen and R.A. Segalman, Macromolecules, 2007, 40(19), 6922-6929.
20. "Domain Size Control in Self-Assembling Rod-Coil Block Copolymer and Homopolymer Blends," Y. Tao, B.D. Olsen, V. Ganesan and R.A. Segalman, Macromolecules, 2007, 40(9), 3320-3327.
19. "Thin Film Structure of Symmetric Rod-Coil Block Copolymers," B.D. Olsen , X. Li, J. Wang and R.A. Segalman, Macromolecules, 2007, 40(9), 3287-3295.
18. "Thermoelectricity in Molecular Junctions," P. Reddy, S.Y. Jang, R.A. Segalman and A. Majumdar, Science, 2007, 315, 1568-1571.
17. "Analysis of Order Formation in Block Copolymer Thin Films using Resonant Soft X-ray Scattering," J. Virgili, Y. Tao, J.B. Kortright, N.P. Balsara and R.A. Segalman, Macromolecules, 2007, 40(6), 2092-2099.
16. "Room temperature thermal conductance of alkanedithiol self-assembled monolayers," R. Wang, R.A. Segalman, and A. Majumdar, Appl Phys Lett, 2006, 89, 173113.
15. "Phase Transitions in Asymmetric Rod-Coil Block Copolymers," B.D. Olsen, R.A. Segalman, Macromolecules, 2006, 39, 7078-7083.
14. "Interpretation of Stochastic Events in Single Molecule Conductance Measurements," P. Reddy, S.Y. Jang, A. Majumdar, R.A. Segalman, Nano Lett, 2006, 6, 2362-2367.
13. "Higher order liquid crystallinity in low polydispersity poly(phenylene vinylenes)," B.D. Olsen, S.Y. Jang, J. Luning, and R.A. Segalman, Macromolecules, 2006; 39(13), 4469-4479.
12. "Structure and Thermodynamics of Weakly Segregated Rod-Coil Block Copolymers," B.D. Olsen and R.A. Segalman, Macromolecules, 2005, 38(24), 10127 - 10137.
11. "Patterning with Block Copolymer Thin Films," R.A. Segalman, Mat Sci Eng R, 2005, 48(6), 191-226.
10. "Solar Cells Based on Diblock Copolymers: A PPV donor block and a fullerene derivatized acceptor block," R.A. Segalman, C. Brochon, G. Hadziioannou, (Book Chapter in Organic Photovoltaics by Sun and Sariciftci, Marcel-Dekker) 2005.
9. "Grain Structure in Block Copolymer Thin Films Studied by Guided Wave Depolarized Light Scattering," Garetz, B. A., Newstein, M. C., Wilbur, J. D., Patel, A. J., Durkee, D. A., Segalman, R.A., Liddle, J. A., Balsara, N. P., Macromolecules, 2005, 38(10), 4282-4288.
8. "Polymer Diffusion in Semicrystalline Polymers Using Secondary Ion Mass Spectroscopy," R.A. Segalman, S. Lustig, E. J. Kramer, Macromolecules, 2004; 37(7); 2613-2617.
7. "Edge Effects on the Order and Melting of a 2D Array of Block Copolymer Spheres," R.A. Segalman, A. Hexemer, E. J. Kramer, Phys Rev Lett 2003, 91(19), 196101.
6. "Effects of Lateral Confinement on Order in Spherical Domain Block Copolymer Thin Films," R.A. Segalman, A. Hexemer, E. J. Kramer, Macromolecules, 2003, 36(18), 6831-6839.
5. "Topographic Templating of Islands and Holes in Highly Asymmetric Block Copolymer Films," R.A. Segalman, K. E. Schaeffer, G. H. Fredrickson, E. J. Kramer, S. Magonov, Macromolecules, 2003, 36(12), 4498-4506.
4. "Ordering and Melting of Block Copolymer Spherical Domains in 2 and 3 Dimensions," R.A. Segalman, A. Hexemer, R. C. Hayward, E. J. Kramer, Macromolecules, 2003, 36(9), 3272-3288.
3. "Graphoepitaxy of Asymmetric Diblock Copolymers," R.A. Segalman, H. Yokoyama, E.J. Kramer, Adv Mater, 2001, 13, 1152.
2. "Dynamics of Rims and the Onset of Spinodal Dewetting at Liquid/Liquid Interfaces," R.A. Segalman, P. F. Green, Macromolecules, 1999; 32(3); 801-807.
1. "Robocasting: Rapid Prototyping of Ceramic Slurries." J. Cesarano, R.A. Segalman, P. Calvert P, Ceramic Industry April 1998; 94-102.