Polymerized Ionic Liquids

Role of Tethered Ion Placement on Polymerized Ionic Liquid Structure and Conductivity: Pendant versus Backbone Charge Placement,” C. M. Evans, C.R. Bridges, G.E. Sonoja, J. Bartels, R. A. Segalman. ACS Macro Letters, 2016, 5, 925-930.

Structure-Conductivity Relationships of Block Copolymer Membranes Based on Hydrated Protic Polymerized Ionic Liquids: Effect of Domain Spacing,” G.E. Sanoja, B.C. Popere, B.S. Beckingham, C.M. Evans, N.A. Lynd, R.A. Segalman. Macromolecules, 2016, 49(6), 2216–2223.

"Anhydrous Proton Transport in Polymerized Ionic Liquid Block Copolymers: Roles of Block Length, Ionic Content, and Confinement," C.M. Evans, G.E. Sanoja, B.C. Popere, R.A. Segalman, Macromolecules, 2016, 49(1), 395-404. DOI: 10.1021/acs.macromol.5b02202

"Improving the Gas Barrier Properties of Nafion via Thermal Annealing: Evidence for Diffusion through Hydrophilic Channels and Matrix," C.M. Evans, M.R. Singh, N.A. Lynd, R.A. Segalman, Macromolecules, 2015, 48(10), 3303-3309.

"Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator," M.A. Modestino, K.A. Walczak, A. Berger, C.M. Evans, S. Haussener, C. Koval, J.S. Newman, J.W. Agerab, R.A. Segalman, Energy Environ. Sci., 2014, 7, 297-301.

"Integrated microfluidic test-bed for energy conversion devices," M.A. Modestino, J.W. Ager III, S. Haussener, R. Gomez-Sjoberg, C. Diaz-Botia, R.A. Segalman, Phys. Chem. Chem. Phys., 2013, 15, 7050-7054.

"Ionic Conduction in Nanostructured Membranes Based on Polymerized Protic Ionic Liquids," Y. Schneider, M.A. Modestino, B.L. McCulloch, M.L. Hoarfrost, R.W. Hess, R.A. Segalman, Macromolecules, 2013, 46(4), 1543-1548.

"Self-assembly and transport limitations in confined Nafion films," M.A. Modestino, D.K. Paul, S. Dishari, S.A. Petrina, F.I. Allen, M.A. Hickner, K. Karan, R.A. Segalman, A.Z. Weber, Macromolecules, 2013, 46(3), 866-873.

"Molecular Solar Thermal (MOST) Energy Storage and Release System," K.M. Poulsen, D. Coso, K. Borjesson, N. Vinokurov, S.K. Meier, K.P.C. Vollhardt, A. Majumdar, R.A. Segalman, Energy and Environmental Science, 2012, 5, 8534-8537.

"Proton Hopping and Long-Range Transport in the Protic Ionic Liquid [Im][TFSI], Probed by Pulsed-Field Gradient NMR and Quasi-Elastic Neutron Scattering," M.L. Hoarfrost, M. Tyagi, R.A. Segalman, J.A. Reimer, J. Phys. Chem. B, 2012, 116(28), 8201-8209.

"Conductivity Scaling Relationships for Nanostructured Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, R.A. Segalman, ACS Macro Letters, 2012, 1, 937-943.

"Controlling Nafion Structure and Properties via Wetting Interactions," M.A. Modestino, A. Kusoglu, A. Hexemer, A. Weber, R.A. Segalman, Macromolecules, 2012, 45(11), 4681-4688.

"Effect of Confinement on Proton Transport Mechanisms in Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, M.S Tyagi, R.A. Segalman, J.A. Reimer, Macromolecules, 2012, 45(7), 3112-3120.

"Sub-second Morphological Changes in Nafion during Water Uptake Detected by Small-Angle X-Ray Scattering," A.Kusoglu, M.A. Modestino, A. Hexemer, R.A. Segalman, A.Z. Weber, ACS Macro Lett, 2012, 1(1), 33-36.

"Ionic Conductivity of Nanostructured Block Copolymer/Ionic Liquid Membranes," M.L. Hoarfrost, R.A. Segalman, Macromolecules, 2011, 44(13), 5281-5288.

"Effect of an Ionic Liquid Solvent on the Phase Behavior of Block Copolymers," J.M. Virgili, M. Hoarfrost, R.A. Segalman, Macromolecules, 2010, 43(12), 5417-5423.

"Ionic Liquid Distribution in Ordered Block Copolymer Solutions," J.M. Virgili, A.J. Nedoma, R.A. Segalman, N.P. Balsara, Macromolecules, 2010, 43(8), 3750-3756.

"Phase Behavior of Polystyrene-block-Poly(2-vinyl pyridine) Copolymers in Selective Ionic Liquid Solvents," J. M. Virgili, A. Hexemer, J. A. Pople, N. Balsara and R.A. Segalman, Macromolecules, 2009, 42, 4604-4613.